2025 SMSI Bannerklein

GS4.2 - A copper(II) oxide – tin dioxide heterojunction sensor for the detection of hydrogen sulfide

Event
17th International Meeting on Chemical Sensors - IMCS 2018
2018-07-15 - 2018-07-19
Vienna, Austria
Chapter
Gas Sensors 4
Author(s)
S. Lehmann - Dräger Safety GmbH & Co KGaA, Lübeck (Germany), M. Bauersfeld, J. Wöllenstein - Fraunhofer IPM, Freiburg (Germany)
Pages
172 - 173
DOI
10.5162/IMCS2018/GS4.2
ISBN
978-3-9816876-9-9
Price
free

Abstract

We present a novel sensor concept for highly sensitive detection of hydrogen sulfide (H2S) using the heterojunction copper(II) oxide - tin dioxide. Unlike other approaches, we use a thin film stack of the semiconductors where the CuO completely covers the SnO2. The basic idea hereby is to prevent the SnO2-layer from the contact of reactive gases in order to reduce cross sensitivities. The films were prepared by reactive electron beam evaporation of copper and tin oxide. Structural and orphological analyses of the films were carried out. The sensitivity, selectivity and stability of the device has been evaluated using several reactive gases including long term tests. The sensor is extremely sensitive to traces of H2S. A slight cross sensitivity to NO2 is observed.

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